Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes.
نویسندگان
چکیده
An improved protocol for the synthesis of [Au(NHC)X] (X = Cl, Br, I) complexes is reported. This versatile one-step synthetic methodology proceeds under mild conditions, in air, using technical grade solvents, is scalable and is applicable to a wide range of imidazolium and imidazolidinium salts.
منابع مشابه
A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes† †Electronic supplementary information (ESI) available: Optimisation details and full characterisation data. CCDC 940850–940853. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45488f Click here for additional data file.
A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 49 شماره
صفحات -
تاریخ انتشار 2013